Synthesis and Characterization of Transition Metal Complexes of New Proton Transfer Salt of 1,4-Pyrazine-2,3-Dicarboxylic Acid
| Autor: | Büyükkıdan, Nurgün, Demir, Nedime |
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| Přispěvatelé: | Büyükkıdan, Nurgün, Demir, Nedime |
| Jazyk: | turečtina |
| Rok vydání: | 2020 |
| Předmět: | |
| Popis: | Bu çalışmada 1,4-pirazin-2,3-dikarboksilik asit (H2pyzdc) ve 2-(piperazin-1-il)etanol (H2Etppz) bileşiklerinin tepkimesinden proton transfer tuzu (H2Etppz)(pyzdc)(1) sentezlendi. Proton transfer tuzunun (1) yapısı; elementel analiz, 1H ve 13C NMR, FTIR ve UV-Vis yöntemlerinden yararlanılarak aydınlatıldı. Proton transfer tuzunun (1) Mn(II) (2), Co(II) (3), Cu(II) (4) ve Zn(II) (5) kompleksleri elde edildi. Komplekslerin yapıları; FTIR, UV-Vis, ICP-OES ve manyetik duyarlılık yöntemleri sonuçlarına göre önerildi. In this study, the proton tansfer salt (H2Etppz)(pyzdc)(1) was synthesized from the reaction of 1,4- pyrazine-2,3-dicarboxylic acid (H2pyzdc) with 2-(piperazine-1-yl)ethanol (H2Etppz). The proton transfer salt (1) was characterized using elemental analysis, 1H and 13C NMR, FTIR, UV-Vis techniques. The Mn(II) (2), Co(II) (3), Cu(II) (4) and Zn(II) (5) complexes of proton transfer salt (1) were synthesized. The structures of the complexes; have been suggested according to results of the FTIR, UV-Vis, ICP-OES and magnetic susceptibility methods. |
| Databáze: | OpenAIRE |
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