Two- and Threefold Intramolecular Bridging p-tert- Butylcalix[8]arene Triphosphates – Synthesis, Structure and Stereochemistry

Autor: Gloede, J., Ozegowski, S., Keitel, I., Gruner, M., Costisella, B., Pritzkow, W., Stephan, H., Bartoschek, M.
Jazyk: angličtina
Rok vydání: 2006
Zdroj: Zeitschrift für Anorganische und Allgemeine Chemie (2006)632, 123-132
Popis: The phosphorylation of p-tert-butylcalix[8]arene (1) with phosphorus pentachloride and hydrolysis gives intramolecular bridging tert-butylcalix[8]arene triphosphates. The reactivity (esterification, dehydratisation, complexation), the structure (nmr and x-ray), and stereochemical behaviour of the phosphates will be discussed.
Databáze: OpenAIRE