Influence of the weak interaction on the structure of metallocycle in binuclear copper(II) complex

Autor: Tomić, Zoran D., Mirković, Marija D., Nikolić, Nadežda S., Stanković, Dragana, Mijin, Dušan Ž., Kapor, Agneš
Jazyk: angličtina
Rok vydání: 2014
Zdroj: Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
Popis: The structure of binuclear Cu(II) complex containing double oximato bridges was determined by the single-crystal X-ray diffraction analysis. Copper is five-coordinated with perchlorato anion present at the borderline of semi-coordination. Comparison with the structurally related diiminedioxime Cu(II) complexes revealed the influence of the weak Cu···O(perchlorate) interaction on the geometry of the metallocycle.
Databáze: OpenAIRE