Thioimidoyl Radicals as a Novel Tin-Free Source of Alkyl Radicals

Autor: BENATI, MARIA LUISA, LEARDINI, RINO, MINOZZI, MATTEO, NANNI, DANIELE, SCIALPI, ROSANNA, SPAGNOLO, PIERO, STRAZZARI, SAMANTHA, ZANARDI, GIUSEPPE, J. C. Walton
Přispěvatelé: L. Benati, R. Leardini, M. Minozzi, D. Nanni, R. Scialpi, P. Spagnolo, S. Strazzari, J. C. Walton, G. Zanardi
Jazyk: angličtina
Rok vydání: 2004
Předmět:
Popis: The radical reaction of alkanethiols with tert-butyl isocyanide in boiling benzene gives rise to intermediate thioimidoyls radicals which undergo easy fragmentation yielding tert-butyl isothiocyanate and corresponding alkyl radicals. These reactions allow a new protocol for the generation of alkyl radicals under tin-free conditions.
Databáze: OpenAIRE