| Autor: |
Seitz, Ann-Katrin, Kohlpaintner, Philipp J. (M. Sc.), Lingen, Tim van (M.Sc.), Dyga, Marco (Dr. rer. nat.), Sprang, Fiona (M. Sc.), Zirbes, Michael, Waldvogel, Siegfried R. (Dr.), Gooßen, Lukas J. (Prof. Dr.) |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Popis: |
Peroxodicarbonates are of substantial interest as potentially powerful and sustainable oxidizers but have so far been accessible only in low concentrations with unsatisfactory energy efficiency. Concentrated (> 0.9 mol \(L^{−1}\)) peroxodicarbonate solutions have now been made accessible by the electrolysis of aqueous \(K_{2}CO_{3}/Na_{2}CO_{3}/KHCO_{3}\) solutions at high current density of 3.33 A \(cm^{−2}\) in an efficiently cooled circular flow reactor equipped with a boron-doped diamond anode and a stainless-steel cathode. Their synthetic potential as platform oxidizers was clearly demonstrated in transformations including sulfoxidation, \(\it N\)-oxidation, and epoxidation. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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