Perovskite/CIGS tandem solar cells

Autor: Jošt, Marko, Köhnen, Eike, Al-Ashouri, Amran, Bertram, Tobias, Tomšič, Špela, Magomedov, Artiom, Kasparavičius, Ernestas, Kodalle, Tim, Lipovšek, Benjamin, Getautis, Vytautas, Schlatmann, Rutger, Kaufmann, Christian A., Albrecht, Steve, Topič, Marko
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: ACS energy letters, vol. 7, no. 4, pp. 1298-1307, 2022.
ISSN: 2380-8195
Popis: We demonstrate a monolithic perovskite/CIGS tandem solar cell with a certified power conversion efficiency (PCE) of 24.2%. The tandem solar cell still exhibits photocurrent mismatch between the subcells thus optical simulations are used to determine the optimal device stack. Results reveal a high optical potential with the optimized device reaching a short-circuit current density of 19.9 mA cm$^{−2}$ and 32% PCE based on semiempirical material properties. To evaluate its energy yield, we first determine the CIGS temperature coefficient, which is at −0.38% K$^{−1}$ notably higher than the one from the perovskite subcell (−0.22% K$^{−1}$), favoring perovskite in the field operation at elevated cell temperatures. Both single-junction cells, however, are significantly outperformed by the combined tandem device. The enhancement in energy output is more than 50% in the case of CIGS single-junction device. The results demonstrate the high potential of perovskite/CIGS tandem solar cells, for which we describe optical guidelines toward 30% PCE.
Databáze: OpenAIRE