| Autor: |
Šturm, Jaka, Modec, Barbara |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Molbank, vol. 2021, no. 3, m1249, 2021. |
| ISSN: |
1422-8599 |
| Popis: |
(PyH)$_2$[MoOCl$_5$] was obtained in the form of emerald green crystals unintentionally from (PyH)$_5$[MoOCl$_4$(H$_2$O)]$_3$Cl$_2$ in acetonitrile. (PyH)$_2$[MoOCl$_5$] has been used as a starting material in molybdenum(V) coordination chemistry for decades, yet its true identity has not been known until now. The X-ray structure analysis has undoubtedly confirmed the existence of this compound. The [MoOCl$_5$]$^{2−}$ ion displays the usual structural characteristics of the mononuclear MoO$^{3+}$-containing compounds. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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