| Autor: |
Brülke, Christine, Heepenstrick, Timo, Sokolowski, Moritz, Krieger, Ina, Wolff, Beatrice, Yang, Xiaosheng, Shamsaddinlou, Ali, Weiß, Simon, Bocquet, François C., Tautz, Frank Stefan, Soubatch, Serguei |
| Jazyk: |
angličtina |
| Rok vydání: |
2019 |
| Předmět: |
|
| Zdroj: |
Physical review / B 99(12), 121404 (2019). doi:10.1103/PhysRevB.99.121404 |
| DOI: |
10.1103/PhysRevB.99.121404 |
| Popis: |
The adsorption geometry, the electronic properties, and the adsorption energy of the prototype organic molecule 3,4,9,10-perylene tetracarboxylic dianhydride (PTCDA) on a monolayer of hexagonal boron nitride (hBN) grown on the Cu(111) surface were determined experimentally. The perylene core is at a large height of 3.37 Å and only a minute downward displacement of the functional anhydride groups (0.07 Å) occurs, yielding adsorption heights that agree with the sum of the involved van der Waals radii. Thus, already a single hBN layer leads to a decoupled (physisorbed) molecule, contrary to the situation on the bare Cu(111) surface. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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