| Autor: |
Dastych, Dalibor, Rotter, Pavel, Demo, Gabriel, Dastychová, Lenka |
| Jazyk: |
angličtina |
| Rok vydání: |
2011 |
| Předmět: |
|
| Zdroj: |
Acta Crystallographica Section E: Structure Reports |
| Popis: |
The title compound, [V2Cl4O2(CH 3CN)4], is a centrosymmetric dinuclear VIV complex associated with four molecules of acetonitrile. The coordination around both VIV atoms is essentially square-planar, involving three Cl atoms and one O atom [maximum deviation = 0.017 (3) Ă… for the O atom]. The augmented octahedral coordination of the metal atom is completed by the N atoms of acetonitrile ligands. The VIV atoms are linked by two Cl atoms, acting as bridging atoms. The crystal studied was a non-merohedral twin with a ratio of the two twin components of 0.8200 (3):0.1800 (3). Although Cl and O atoms are present as potential acceptors in the title compound, no hydrogen bonds were observed in the crystal structure. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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