| Autor: |
SHARUTIN V.V., SHARUTINA O.K., ARTEM'EVA E.V., MAKEROVA M.S. |
| Jazyk: |
ruština |
| Rok vydání: |
2015 |
| Předmět: |
|
| Zdroj: |
Вестник Южно-Уральского государственного университета. Серия: Химия. |
| ISSN: |
2076-0493 |
| Popis: |
Tri( o-tolyl)antimony oxidation by equimolar amount of tert-butyl hydroperoxide in diethyl ether led to the formation of bis[µ 2-oxo-tri( o-tolyl)antimony] (1). At the molar ratio of reactants 1:2 or 1:4 µ 2-oxobis[( tert-butylperoxy)tri( o-tolyl)antimony] (2) has been formed. According to the X-ray analysis data, antimony atoms are in the trigonal bipyramidal coordination in molecules 1 and 2. The bond lengths Sb-O vary within the ranges 1.937(2)-2.078(2) Å (1) and 1.975(17)-2.216(15) Å (2). |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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