Strain fluctuations in BaTiO₃/SrTiO₃ heterostructures

Autor: Gartnerova, V. (V.), Pacherova, O. (O.), Klinger, M. (M.), Jelinek, M. (M.), Jager, A. (A.), Tyunina, M. (M.)
Jazyk: angličtina
Rok vydání: 2017
Předmět:
Popis: Epitaxy of perovskite oxide ferroelectric heterostructures with large lattice misfit is crucial for numerous emerging applications. Here we demonstrate cube-on-cube-type epitaxial growth of BaTiO₃ films on strongly mismatched (001)SrTiO₃ single-crystal substrates for the films with thicknesses significantly larger than that of misfit relaxation. The films experience strain originating from the film-substrate thermal expansion mismatch. Using a dedicated digital analysis of electron microscopy images, we show that the films contain random nanoregions of substantial strain fluctuations: the local strains vary in the range of ∼(0.5–2)% compared with the average strain magnitude of ∼1%. Because of strong strain-polarization coupling in ferroelectrics, fluctuations of strain produce fluctuations of polarization, which are suggested to cause relaxor-like properties in many mismatched heterostructures.
Databáze: OpenAIRE