| Popis: |
The perchlorate Ion selective electrode has been used as a periodate sensor. The electrode gave near-Nernstian response from 10-1 to 10-5 M periodate, with a slope of 62-58 at pH 4.0 depending on the electrode age. lodate, the usual product in periodate organic reactions does not Interfere with periodate determination. Response data prove that the perchlorate electrode can be used for continuous monitoring of periodate reactions. Several periodate-vicinal glycol reactions have been studied and equilibrium and rate constants have been determined. Kinetic data obtained with the electrode compare favorably with those obtained by tedious sampling techniques. © 1977, American Chemical Society. All rights reserved. |
