Popis: |
Size-segregated aerosols (six stages with a diameter from 7.2 μm) were collected during daytime and nighttime in the summer of 2020 and were analyzed for dicarboxylic acids, isoprene, α/β-pinene and β-caryophyllene secondary organic aerosol (SOA) tracers, aromatic acids, hydroxy-polyacids, monocarboxylic acids and levoglucosan. The vast majority of the detected compounds presented significantly higher (p < 0.05) concentrations in fine than in coarse modes, excluding benzoic and oleic acids for which the higher fine mode than coarse mode concentrations were not significant and pinonic acid which was found at higher coarse mode concentrations. The dominant compound in the fine mode was 2-methylerythritol (mean of 213 ± 79.4 ng m−3), whereas in coarse particles palmitic acid was the most abundant (mean of 22.8 ± 9.7 ng m−3). All of the detected compounds, except for terephthalic acid, presented higher daytime concentrations, a difference that in the cases of glutaric, suberic, azelaic and pinic acids was significant (p < 0.05). The six-stage size distribution showed various patterns, with most species peaking at particles with a diameter of |