| Autor: |
Qianli Chu Andrew J. E. Duncan Giannis S. Papaefstathiou Tamara D. Hamilton Manza B. J. Atkinson S. V. Santhana Mariappan Leonard R. MacGillivray |
| Jazyk: |
angličtina |
| Rok vydání: |
2018 |
| Předmět: |
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| Popis: |
Enlargement of a self-assembled metal organic rhomboid is achieved via the organic solid state. The solid-state synthesis of an elongated organic ligand was achieved by a template directed [2 + 2] photodimerization in a cocrystal. Initial cocrystals obtained of resorcinol template and reactant alkene afforded a 1:2 cocrystal with the alkene in a stacked yet photostable geometry. Cocrystallization performed in the presence of excess template resulted in a 3:2 cocrystal composed of novel discrete 10-component hydrogen-bonded “superassemblies” wherein the alkenes undergo a head-to head [2 + 2] photodimerization. Isolation and reaction of elongated photoproduct with Cu(II) ions afforded a metal-organic rhomboid of nanoscale dimensions that hosts small molecules in the solid state as guests. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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