| Autor: |
Stemer, D., Buttersack, T., Haak, H., Malerz, S., Schewe, H., Trinter, F., Mudryk, K., Pugini, M., Credidio, B., Seidel, R., Hergenhahn, U., https://orcid.org/0000-0003-3396-4511, Meijer, G., https://orcid.org/0000-0001-9669-8340, Thürmer, S., Winter, B. |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Zdroj: |
The Journal of Chemical Physics |
| Popis: |
We demonstrate liquid-jet photoelectron spectroscopy from a flatjet formed by the impingement of two micron-sized cylindrical jets of different aqueous solutions. Flatjets provide flexible experimental templates enabling unique liquid-phase experiments that would not be possible using single cylindrical liquid jets. One such possibility is to generate two co-flowing liquid-jet sheets with a common interface in vacuum, with each surface facing the vacuum being representative of one of the solutions, allowing face-sensitive detection by photoelectron spectroscopy. The impingement of two cylindrical jets also enables the application of different bias potentials to each jet with the principal possibility to generate a potential gradient between the two solution phases. This is shown for the case of a flatjet composed of a sodium iodide aqueous solution and neat liquid water. The implications of asymmetric biasing for flatjet photoelectron spectroscopy are discussed. The first photoemission spectra for a sandwich-type flatjet comprised of a water layer encapsulated by two outer layers of an organic solvent (toluene) are also shown. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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