| Autor: |
Gromovoy, Yu., Basiuk, E.V., Pokrovskiy, V.A., Chuiko, A.A. |
| Jazyk: |
angličtina |
| Rok vydání: |
2002 |
| Předmět: |
|
| Popis: |
The gas-phase derivatization procedure was employed for direct (i.e., without chemical activation of terminal carboxylic groups) amidization of oxidized single-walled carbon nanotubes (SWNTs) with simple aliphatic amines. The procedure includes treatment of SWNTs with amine vapors under reduced pressure and temperature of 160-170ºC. Applicability of temperature-programmed desorption mass spectrometry for chemical characterization of the derivatized SWNTs was analyzed. Heating of the amine-treated SWNTs at temperature >200ºC causes cleavage of alkenes from the amine residues: nonene and pentene are formed in the case of nonylamine and dipentylamine, respectively. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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