Autor: |
Fomenko, L.S., Lubenets, S.V., Natsik, V.D., Cassidy, D., Gadd, G.E., Moricca, S., Sundqvist, B. |
Jazyk: |
angličtina |
Rok vydání: |
2005 |
Předmět: |
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Popis: |
The Vickers microhardness of Xe-intercalated polycrystalline fullerite C₆₀ (XexC₆₀, x ≃ 0.35) is measured in a moderately low temperature range of 77 to 300 K. A high increase in the microhardness of the material (by a factor of 2 to 3) as compared to that of pure C₆₀ single crystals is observed. It is shown that the step-like anomaly in the temperature dependences of the microhardness of pure C₆₀ single crystals recorded under the orientational fcc-sc phase transition (Tc ≃ 260 K) is also qualitatively retained for XexC₆₀, but its onset is shifted by 40 K towards lower temperatures and the step becomes less distinct and more smeared. This behavior of ̅NV(T) correlates with x-ray diffraction data, the analysis of which revealed a considerable influence of xenon interstitial atoms on the peculiar features of fullerite thermal expansion due to orientational phase transitions (see the paper by A.I. Prokhvatilov et al. in this issue). |
Databáze: |
OpenAIRE |
Externí odkaz: |
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