Thermodynamically Preferred Axial Allylic -NHTs Substituent in Simple 1-Triisopropylsilyl(oxy) Cyclohexenes: Solid State Conformation by X-ray Crystallography

Autor: Magnus, Philip, Lacour, Jérôme, Bauta, William, Mugrage, Benjamin, Lynch, Vincent
Jazyk: angličtina
Rok vydání: 1991
Předmět:
Zdroj: Journal of the Chemical Society. Chemical Communications, No 19 (1991) pp. 1362-1364
ISSN: 0022-4936
Popis: For a series of 6-(4-methylphenylsulphonyl)amino-1-triisopropylsilyl(oxy)-cyclohexenes the preferred conformation, in the solid state, has the –NHTs (Ts = 4-methylphenylsulphonyl) group in an axial orientation; if the axial-NHTs group experiences a 1,3-diaxial interaction with a methyl group, the equatorial conformation becomes the thermodynamically more stable form.
Databáze: OpenAIRE