| Autor: |
BERINGHELLI, T, CIANI, G, DALFONSO, G, GARLASCHELLI, L, SIRONI, A., MORET, MASSIMO |
| Přispěvatelé: |
Beringhelli, T, Ciani, G, Dalfonso, G, Garlaschelli, L, Moret, M, Sironi, A |
| Jazyk: |
angličtina |
| Rok vydání: |
1992 |
| Předmět: |
|
| Popis: |
The unsaturated molecule [Re2(mu-H)2(CO)8] adds [Ir(CO)4] - at -80-degrees-C to give the anion [(OC)4HRe-(mu-H) Re(CO)4Ir(CO)4]-, which at higher temperatures transforms into the triangular cluster [Re2IrH2-(CO)11] -; the latter, by reductive coupling with itself or with [ReH(CO)5],affords [{Re2lr(mu-H)(CO)11}2]2 and [Re3Ir(mu-H)(CO)15]-, respectively, which have been characterized by X-ray diffraction. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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