| Autor: |
BERINGHELLI, T, DALFONSO, G, CIANI, G, SIRONI, A., MORET, MASSIMO |
| Přispěvatelé: |
Beringhelli, T, Dalfonso, G, Ciani, G, Moret, M, Sironi, A |
| Jazyk: |
angličtina |
| Rok vydání: |
1993 |
| Předmět: |
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| Popis: |
The reaction of the unsaturated dinuclear molecule [Re2(mu-H)2(CO)8] with CS2 affords in good yield the complex [{Re2(mu-H)(CO)8}2(mu4-S2CH2)], containing a methanedithiolate H2CS2 fragment originated by the transfer of two hydrides, presumably one from each metal complex, to CS2. The molecule has been characterized spectroscopically and by single-crystal X-ray diffraction analysis. The crystals are monoclinic, space group P2(1)/c, with a = 13.559(1), b = 12.502(1), c = 16.718(1) angstrom, beta = 99.26(1)-degrees. The structure was refined on the basis of 2689 significant reflections to a final R value of 0.026. The molecule consists of two Re2(mu-H)(CO)8 units linked by a methanedithiolate ligand. Each sulfur atom bridges two Re atoms belonging to the same dinuclear moiety. The overall idealized symmetry of the molecule is C2. The average Re-Re and Re-S bond lengths are 3.089 and 2.475 angstrom, respectively. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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