Hydrogen activation with perfluorinated organoboranes: 1,2,3- tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene
| Autor: | Houghton, Adrian Y., Karttunen, Virve, Piers, Warren E., Tuononen, Heikki |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Popis: | The perfluorinated boraindene 3 was synthesized and fully characterized. Both computational and crystallographic data show that 3 is antiaromatic. Compound 3 was shown to react reversibly with H2 and to catalyse the hydrogenation of cyclohexene. The mechanism of catalysis was probed experimentally and computationally. peerReviewed |
| Databáze: | OpenAIRE |
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