| Autor: |
Troy, Tyler P., Chalyavi, Nahid, Menon, Ambili S., O'Connor, Gerard D., Fückel, Burkhard, Nauta, Klaas, Radom, Leo, Schmidt, Timothy W. |
| Jazyk: |
angličtina |
| Rok vydání: |
2011 |
| Předmět: |
|
| Popis: |
The resonant two-color two-photon ionization and laser induced fluorescence excitation spectra of the 1-phenylallyl (cinnamyl) and inden-2-ylmethyl radicals are reported. The 1-phenylallyl radical is found to fluoresce with low yield, permitting only a coarse dispersed fluorescence spectrum, while the inden-2-ylmethyl radical yields sufficient fluorescence to obtain ground-state vibrational frequencies and two-dimensional fluorescence spectra. Computed ionization energies and thermochemical properties including radical stabilization energies are reported for a range of resonance-stabilized radicals, including the phenylpropargyl, vinylpropargyl and phenylallyl radicals. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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