Oxidative Addition of Diethylchalcogenanes to Lapperts Germylene and Stannylene

Autor: Bendt, Georg, Lapsien, Silvia, Steiniger, Phillip, Bläser, Dieter, Wölper, Christoph, Schulz, Stephan
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Popis: Oxidative addition of diethyldichalcogenanes Et2E2 (E = S, Se, Te) to bis[bis(trimethylsilyl]amido]germylene and ‐stannylene M[N(SiMe3)2]2 (M = Ge, Sn) proceed with formation of the corresponding bis(ethylchalcogenato)germanes (Me3Si)2N)2Ge(EEt)2 [E = S (1), Se (2), Te (3)] and ‐stannanes (Me3Si)2N)2Sn(EEt)2 [E = S (4), Se (5), Te (6)]. The solid state structures of 1–6 were determined by single‐crystal X‐ray diffraction.
Databáze: OpenAIRE