| Autor: |
Chen, C, Li, D, Gao, L, Harks, PPRML, Eichel, RA, Notten, PHL |
| Jazyk: |
angličtina |
| Rok vydání: |
2017 |
| Předmět: |
|
| Popis: |
Li2S has made the concept of Li-S batteries much more promising due to the relatively high storage capacity, the possibility of using Li-free anodes and the increase of microstructural stability. However, similar to S, Li2S also suffers from an insulating nature and polysulfide dissolution problem. The results presented here show a facile and cost-effective approach by using a plasma sparking and chemical sulfurization process to synthesize core-shell Li2S@C nanocomposites. The nanocomposites show a significantly reduced particle size and well-developed core-shell architecture, effectively shortening the Li-ion diffusion distance, enhancing the electronic conductivity and suppressing the dissolution losses of polysulfides. As a result, a much improved rate and cycling performance has been achieved. The method presented in this study offers good opportunities for scaling up the production of high performance cathode materials in a simple and low-cost way to be applied in future generation Li-S batteries. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
