| Autor: |
Kim, KC, Hauke, F, Hirsch, A, Boyd, PDW, Carter, E, Armstrong, RS, Lay, PA, Reed, CA |
| Jazyk: |
angličtina |
| Rok vydání: |
2003 |
| Zdroj: |
Kim, KC; Hauke, F; Hirsch, A; Boyd, PDW; Carter, E; Armstrong, RS; et al.(2003). Synthesis of the C59N+ carbocation. A monomeric azafullerene isoelectronic to C60. Journal of the American Chemical Society, 125(14), 4024-4025. doi: 10.1021/ja034014r. UC Riverside: Retrieved from: http://www.escholarship.org/uc/item/9zm1w8x3 |
| DOI: |
10.1021/ja034014r. |
| Popis: |
A heterofullerene isoelectronic to C60 is reported. The azafullerenium cation C59N+ can be isolated in good yield as a carborane salt via the two-electron oxidation of the C-C bond of (C59N)2 dimer. [C59N][Ag(CB11H6Cl6)2] has been characterized by electronic, IR, Raman, and 13C NMR spectroscopies, MALDI spectrometry, DFT calculations, and X-ray crystallography. Copyright © 2003 American Chemical Society. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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