| Autor: |
Nguyen, TAD, Goldsmith, BR, Zaman, HT, Wu, G, Peters, B, Hayton, TW |
| Jazyk: |
angličtina |
| Rok vydání: |
2015 |
| Zdroj: |
Nguyen, TAD; Goldsmith, BR; Zaman, HT; Wu, G; Peters, B; & Hayton, TW. (2015). Synthesis and characterization of a Cu14 hydride cluster supported by neutral donor ligands. Chemistry-A European Journal, 21(14), 5341-5344. doi: 10.1002/chem.201500422. UC Santa Barbara: Retrieved from: http://www.escholarship.org/uc/item/6xt1t98c |
| DOI: |
10.1002/chem.201500422. |
| Popis: |
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The copper hydride clusters [Cu14H12(phen)6(PPh3)4][X]2 (X=Cl or OTf; OTf=trifluoromethanesulfonate, phen=1,10-phenanthroline) are obtained in good yields by the reaction of [(Ph3P)CuH]6 with phen, in the presence of a halide or pseudohalide source. The complex [Cu14H12(phen)6(PPh3)4][Cl]2 reacts with CO2 in CH2Cl2, in the presence of excess Ph3P, to form the formate complex [(Ph3P)2Cu(κ2-O2CH)], along with [(phen)(Ph3P)CuCl]. The copper hydride clusters [Cu14H12(phen)6(PPh3)4][X]2 (X=Cl or OTf; OTf=trifluoromethanesulfonate, phen=1,10-phenanthroline) were obtained in good yields by the reaction of [(Ph3P)CuH]6 with phen, in the presence of a halide or pseudohalide source. This work demonstrates that [(Ph3P)CuH]6 is a viable precursor for the generation of high nuclearity copper clusters. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
