| Autor: |
Rauscher, JF, Condron, CL, Beault, T, Kauzlarich, SM, Jensen, N, Klavins, P, Maquilon, S, Fisk, Z, Olmstead, MM |
| Jazyk: |
angličtina |
| Rok vydání: |
2009 |
| Zdroj: |
Rauscher, JF; Condron, CL; Beault, T; Kauzlarich, SM; Jensen, N; Klavins, P; et al.(2009). Flux growth and structure of two compounds with the EuIn2P2structure type, AIn2P2(A = Ca and Sr), and a new structure type, BaIn2P2. Acta Crystallographica Section C: Crystal Structure Communications, 65(10), i69-i73. doi: 10.1107/S0108270109035987. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/6sb0r7w1 |
| DOI: |
10.1107/S0108270109035987. |
| Popis: |
Single crystals of the new Zintl phases AIn2P2[A = Ca (calcium indium phosphide), Sr (strontium indium phosphide) and Ba (barium indium phosphide)] have been synthesized from a reactive indium flux. CaIn2P2and SrIn2P2are isostructural with EuIn2P2and crystallize in the space group P63/mmc. The alkaline earth cations A are located at a site with m symmetry; In and P are located at sites with 3m symmetry. The structure type consists of layers of A2+cations separated by [In2P2]2-anions that contain [In2P6] eclipsed ethane-like units that are further connected by shared P atoms. This yields a double layer of six-membered rings in which the In - In bonds are parallel to the c axis and to one another. BaIn2P2crystallizes in a new structure type in the space group P21/m with Z = 4, with all atoms residing on sites of mirror symmetry. The structure contains layers of Ba2+cations separated by [In2P2]2-layers of staggered [In2P6] units that form a mixture of four-, five- and six-membered rings. As a consequence of this more complicated layered structure, both the steric and electronic requirements of the large Ba2+cation are met. © 2009 International Union of Crystallography. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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