Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding

Autor: Ostrovsky, S., Tomkowicz, Z., Foro, S., Reedijk, J., Haase, W.
Jazyk: angličtina
Rok vydání: 2020
Popis: The new mononuclear [Co(dbz)Cl-2] (dbz = bis(2-benzimidazolyl)ethane) complex has been studied by magnetic measurements and variable-temperature, variable-field magnetic circular dichroism (MCD) spectroscopy, accompanied by theoretical modelling. The values of the zero-field splitting parameters obtained from different experimental techniques are compared with the quantum-chemical calculations. (C) 2020 Elsevier Ltd. All rights reserved.
Databáze: OpenAIRE