Origin of faceted surface hillocks on semi-polar (1 1 2 ¯ 2) GaN templates grown on pre-structured sapphire

Autor: Han, Y, Caliebe, M, Kappers, M, Scholz, F, Pristovsek, M, Humphreys, C
Přispěvatelé: Han, Y [0000-0002-7638-6785], Apollo - University of Cambridge Repository
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Popis: The microstructure of semi-polar (1 1 2 2) GaN templates grown on pre-structured r-plane sapphire by metal–organic vapor phase epitaxy (MOVPE) followed by hydride vapor phase epitaxy (HVPE) has been characterised by transmission electron microscopy (TEM). It is found that dislocations originating from the inclined c-plane-like GaN/sapphire interface bend and then terminate either at the coalescence regions of the adjacent GaN stripes or at the SiO2 mask. However, the regions associated with the coalescence event during the MOVPE growth act as a source of dislocations and stacking faults in the subsequent growth process. More importantly, a direct link between the formation of a surface hillock, the presence of an inversion domain, and the preferential nucleation of randomly oriented GaN particles at a region containing a dislocation bundle originating from coalescence has been established. It is suggested that controlling the surface conditions of the MOVPE GaN layer before HVPE and optimising the HVPE nucleation process are important to avoid the surface hillocks.
Databáze: OpenAIRE