Identifikacija i sinteza odabranih sastojaka voskova biljnih vrsta Prima veris L., Primula acaulis(L.) L. (Primulaceae) I Liriodendron tulipifera L. (Magnoliaceae)
| Autor: | Živković Stošić, Milena |
|---|---|
| Přispěvatelé: | Radulović, Niko, Stojanović, Gordana, Zlatković, Bojan, Genčić, Marija S., Dekić, Milan S. |
| Jazyk: | srbština |
| Rok vydání: | 2022 |
| Předmět: |
Primula veris L.
Primula acaulis (L.) L. Liriodendron tulipifera L. plant wax cuticle washings biosynthesis organic synthesis alkanes alkenes fatty acid benzyl esters aldehydes alkanones syn-1- phenylalkane-1 3-diyl diacetates 3-oxo-1-phenylalkan-1-yl acetates 1-phenylalkane-1 3-diones 1-hydroxy-1-phenylalkan-3-ones longchain alkanols long-chain fatty acids hydroxyketones Primula veris L. Primula acaulis (L.) L. Liriodendron tulipifera L. vosak kutikula ispirak biosinteza organska sinteza alkani alkeni benzil-estri masnih kiselina aldehidi alkanoni 1-fenil-1 3-alkadiil-diacetati 3-okso-1-fenilalkil-acetati 1-fenil-1 3-alkadioni 1-fenil-1-hidroksi-3-alkanoni dugolančani alkoholi dugolančane masne kiseline hidroksi- ketoni |
| Zdroj: | Универзитет у Нишу |
| Popis: | This doctoral dissertation presents the chemical composition of the washings of Primula veris L., Primula acaulis (L.) L. and Liriodendron tulipifera L. The studied Primula species were rich in long-chain branched alkanes. For the first time, 19 new long-chain n-, iso-, and anteiso-benzyl alkanoates, as well as 8 iso- and 6 anteiso-2- alkanones were identified in samples of natural origin. Evennumbered iso-alkanes and 2-alkanones, and iso-odd-numbered fatty acid benzyl esters, are unique for Primula spp. Washings of P. veris contained new: 16 syn-1-phenylalkane-1,3-diyl diacetates, 7 3-oxo-1- phenylalkan-1-yl acetates, 8 1-phenylalkane-1,3-diones, and 10 1- Hydroxy-1-phenylalkan-3-ones, with n-, iso- and anteiso-chaintermini. Also, 79 n-, iso-, and anteiso-sec-alcohols were identified (66 new), and 77 long-chain n-, iso-, anteiso-, 2-methyl-, and 3- methylfatty acids. All long-chain 2-methyl- and 3-methyl acids were found in the Plant Kingdom for the first time. Benzyl esters lower the wax melting point, which increases the permeability of the cuticle, and reduce the harmful effects of UV-C radiation. Washings of L. tulipifera flowers, among the most abundant palmitone, contained nalkanes, (E)-n-alkenes, regioisomeric alk(en)als, alkanones, and (Z)- alk(en)-1-ols. Double bond regiochemistry was inferred from DMDS adducts MS. Where possible, the configuration was inferred from the NMR analysis of cyclopropanation adducts. 10/11-Hydroxy-16- hentriacontanones were identified based on the analysis of trimethylsilyl derivatives of hydroxy-ketone and bis(trimethylsilyl) derivatives of hentriacontanediols MSes. GC-MS analysis of L. tulipifera leaf washings samples revealed that the main constituent was palmitone, while separate GC-MS analyses of petals, sepals, and pistils with anthers, revealed palmitone to be predominant on the petal and sepal surfaces. |
| Databáze: | OpenAIRE |
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