| Autor: |
Chakraborty, U., Mühldorf, B., van Velzen, N.J.C., de Bruin, B., Harder, S., Wolf, R. |
| Přispěvatelé: |
Sustainable Chemistry, HIMS Other Research (FNWI), Faculty of Science, Nature Inspired Transition Metal Catalysis (HIMS, FNWI) |
| Jazyk: |
angličtina |
| Rok vydání: |
2016 |
| Zdroj: |
Inorganic Chemistry, 55(6), 3075-3078. American Chemical Society |
| ISSN: |
0020-1669 |
| Popis: |
The 17 valence electron (VE) open-shell nickel gallanediyl complex [CpArNi{Ga(nacnac)}] (3, Ar = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N(C6H3-2,6-iPr2)]2), having an unsupported Ni–Ga bond, was synthesized from [CpArNi(μ-Br)]2 (1) by reducing the adduct [CpArNi(μ-Br){Ga(nacnac)}] (2) or, alternatively, trapping the “CpArNiI” synthon with Ga(nacnac); spectroscopic and DFT studies showed that the single unpaired electron in 3 resides mainly at the Ni center. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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