Relationship between domain-boundary free energy and the temperature dependence of stress-domain patterns

Autor: van Gastel, Raoul, Bartelt, N.C., Feibelman, P.J., Leonard, F., Kellogg, G.L.
Přispěvatelé: Physics of Interfaces and Nanomaterials, Faculty of Science and Technology
Rok vydání: 2004
Předmět:
Zdroj: Physical review B: Condensed matter and materials physics, 70(24). American Physical Society
ISSN: 1098-0121
Popis: Pb deposition on Cu(111) causes the surface to self-assemble into periodically arranged domains of a Pb-rich phase and a Pb-poor phase. Using low-energy electron microscopy (LEEM) we provide evidence that the observed temperature-dependent periodicity of these self-assembled domain patterns is the result of changing domain-boundary free energy. We determine the free energy of boundaries at different temperatures from a capillary wave analysis of the thermal fluctuations of the boundaries and find that it varies from 22 meV/nm at 600 K to 8 meV/nm at 650 K. Combining this result with previous measurements of the surface stress difference between the two phases we find that the theory of surface-stress-induced domain formation can quantitatively account for the observed periodicities.
Databáze: OpenAIRE