Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

Autor: Gómez, Rafael, Duchateau, Robbert, Chernega, Alexander N., Teuben, Jan H., Edelmann, Frank T., Green, Malcolm L.H.
Jazyk: angličtina
Rok vydání: 1995
Zdroj: Journal of Organometallic Chemistry, 491, 153-158. Elsevier Science
ISSN: 0022-328X
Popis: The new compounds {M(η-C5R5)[η-CPh(NSiMe3)2]]Cl2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(η-C5R5)([η-CPh(NSiMe3)2]Cl2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(η-C5H5)[η-CPh(NSiMe3)2]Cl2} acts as a co-catalyst for the polymerisation of ethylene and propene.
Databáze: OpenAIRE