Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium
Autor: | Gómez, Rafael, Duchateau, Robbert, Chernega, Alexander N., Teuben, Jan H., Edelmann, Frank T., Green, Malcolm L.H. |
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Jazyk: | angličtina |
Rok vydání: | 1995 |
Zdroj: | Journal of Organometallic Chemistry, 491, 153-158. Elsevier Science |
ISSN: | 0022-328X |
Popis: | The new compounds {M(η-C5R5)[η-CPh(NSiMe3)2]]Cl2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(η-C5R5)([η-CPh(NSiMe3)2]Cl2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(η-C5H5)[η-CPh(NSiMe3)2]Cl2} acts as a co-catalyst for the polymerisation of ethylene and propene. |
Databáze: | OpenAIRE |
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