| Autor: |
Kloosterziel, H., Zwanenburg, E. |
| Přispěvatelé: |
Chemical Engineering and Chemistry |
| Jazyk: |
angličtina |
| Rok vydání: |
1969 |
| Zdroj: |
Recueil des Travaux Chimiques des Pays-Bas, 88(12), 1373-1376. Royal Netherlands Chemical Society |
| ISSN: |
0165-0513 |
| Popis: |
NMR spectroscopy has revealed that the bicyclo[5.1.0]octadienyl anion (I) isomerizes by opening of the three-membered ring and a 1,2 shift of h to the 1,6-methanoheptatrienyl anion. The symmetry-forbidden electrocyclic ring opening of I to the cyclooctatrienyl anion (II) does not occur. Expts. with cycloocta-1,3,5-triene showed that II is unstable relative to disproportionation into cyclooctatriene and cyclooctatetraenyl dianion. [on SciFinder (R)] |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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