| Autor: |
Steemers, L., Wanner, M.J., van Leeuwen, B.R.C., Hiemstra, H., van Maarseveen, J.H. |
| Přispěvatelé: |
Synthetic Organic Chemistry (HIMS, FNWI), Faculty of Science |
| Jazyk: |
angličtina |
| Rok vydání: |
2018 |
| Zdroj: |
European Journal of Organic Chemistry, 2018(7), 874-878. Wiley-VCH Verlag |
| ISSN: |
1434-193X |
| Popis: |
A templated backfolding concept to construct a [2]catenane was attempted via a quasi[1]catenane showing an inverted spiro geometry. The template is covalently connected to the ketal-connected semi-perpendicular-arranged linear precursors and spatially directs the sterically congested backfolding macrocyclizations that are required to give a quasi[1]catenane. So far, we are unable to hydrolyze the cyclic ketal to liberate the [2]catenane. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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