Dichloro{2,2'-thiobis[(4S)-4-isopropyl-1,3-oxazolinylphenyl]}zinc(II): Section Title: Crystallography and Liquid Crystals

Autor:	Kooijman, Huub, Spek, Anthony L., Zondervan, Charon, Feringa, Bernard
Přispěvatelé:	Synthetic Organic Chemistry
Jazyk:	angličtina
Rok vydání:	2002
Předmět:	Molecular structure (of zinc chloro thiobis(isopropyloxazolinylphenyl) complex) mol Crystal structure zinc structure thiobisphenylisopropyloxazoline crystal
Zdroj:	Acta Crystallographica, Section E: Structure Reports Online, 58(8), m429-m431. BLACKWELL PUBLISHING
ISSN:	1600-5368
Popis:	Crystals of the title compd. are orthorhombic, space group P212121, with a 9.5848(6), b 15.6021(9), c 16.4734(9) Ã…; Z = 4, dc = 1.469; R = 0.028, Rw(F2) = 0.063 for 5650 reflections. The compd. consists of a tetrahedral Zn atom coordinated by a C2-sym. bis-oxazoline ligand. To participate in complexation, the ligand becomes bowl-shaped, which results in a distance between the Zn and S atoms of 5.2237(8) Ã…. [on SciFinder(R)]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=narcis______::94a02e2799b77f627c11aadcb5937d04 https://research.rug.nl/en/publications/e88e0403-1a1a-4638-b901-abcc7783bd6b Zobrazit plný text záznamu Plný text