LIPASE-CATALYZED RESOLUTIONS OF SOME ALPHA,ALPHA-DISUBSTITUTED 1,2-DIOLS IN ORGANIC-SOLVENTS - NEAR ABSOLUTE REGIO AND CHIRAL RECOGNITION

Autor:	HOF, RP, KELLOGG, RM
Přispěvatelé:	Molecular Inorganic Chemistry
Jazyk:	angličtina
Rok vydání:	1994
Předmět:	organic chemicals ENANTIOMERS fungi food and beverages ALCOHOLS macromolecular substances ALKYLATION ACIDS ALDEHYDES
Zdroj:	Tetrahedron-Asymmetry, 5(4), 565-568. PERGAMON-ELSEVIER SCIENCE LTD
ISSN:	0957-4166
Popis:	Several racemic 1,2-diols bearing a tertiary benzylic alcohol stereogenic center can be esterified regioselectively by vinyl acetate using lipases and esterases in organic media. With the correct choice of enzyme and if the non-phenyl substituent at the tertiary center is unsaturated, E values of > 250 can be achieved.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=narcis______::7ee561efe2c84b8192536ab398c89684 https://research.rug.nl/en/publications/39248874-dec8-496d-9ae3-6e6f1a7f78f5 Zobrazit plný text záznamu