| Autor: |
Struck, Oliver, Verboom, Willem, Reinhoudt, David N. |
| Přispěvatelé: |
Faculty of Science and Technology, Molecular Nanofabrication |
| Jazyk: |
němčina |
| Rok vydání: |
1996 |
| Zdroj: |
GIT, 40(6), 640-642. GIT Verlag |
| ISSN: |
0016-3538 |
| Popis: |
A new strategy for the synthesis of molecular cavities was developed by the covalent linkage of relatively rigid macrocydes (calix[4]- and resorcin[4]arenes) which themselves possess a permanent cavity. The stepwise coupling of the respective building blocks gives carceplexes (host-guest compounds) which have trapped guest molecules in their interior. These carceplexes exhibit a novel type of stereoisomerism (carceroisomerism) as a result of different orientations of the guest molecules inside the cavity. The convergent, cyclic combination of two calix[4]- and two resorcin[4]arene building blocks gives a large artifical receptor molecule (holand). The holand contains a permanent cavity of nanosize dimensions which is extremely rigid for its size. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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