NOVEL SILICON BISALKOXY COMPLEXES WITH A PSEUDO-ATRANE STRUCTURE - SYNTHESIS AND MOLECULAR-STRUCTURES OF 2,6-DI(2-HYDROXY(2-ADAMANTYL))ETHYLPYRIDINE AND 2,6-DI(2-OXY(2-ADAMANTYLIDINE))ETHYLPYRIDINE DIMETHYLSILICON

Autor: EDEMA, JJH, LIBBERS, R, RIDDER, A, KELLOGG, RM, SPEK, AL, Libbers, Rob
Přispěvatelé: Molecular Inorganic Chemistry
Jazyk: angličtina
Rok vydání: 1994
Předmět:
Zdroj: Journal of Organometallic Chemistry, 464(2), 127-131. Elsevier Science
ISSN: 0022-328X
Popis: Reaction of 2,6-lutidine with 2 equivalents of (n)BuLi followed by addition of 2-adamantanone affords the doubly functionalized 2,6-di-(2-oxy(2-adamantylidine))ethylpyridine (2a). Reaction of 2a with Me(2)SiCl(2) gives the pseudo-pentacoordinate 2,6-di-(2-oxy(2-adamantylidine))-ethylpyridinedimethylsilicon (4). The structures of 2a and 4 have been determined by an X-ray diffraction study.
Databáze: OpenAIRE