Spin Crossover and Thermochromism in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)-4-methoxypyridine

Autor: Lavrenova, Olga G. Shakirova, Irina A. Os’kina, Evgeniy V. Korotaev, Sergey A. Petrov, Natalia V. Kuratieva, Alexsei Ya. Tikhonov, Lyudmila G.
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: International Journal of Molecular Sciences; Volume 24; Issue 12; Pages: 9853
ISSN: 1422-0067
DOI: 10.3390/ijms24129853
Popis: New iron(II) complexes with 2,6-bis(1H-imidazol-2-yl)-4-methoxypyridine (L) of the composition [FeL2]An∙mH2O (A = SO42−, n = 1, m = 2 (I); A = ReO4−, n = 2, m = 1 (II); A = Br−, n = 2, m = 2 (III)) have been synthesized and investigated. To determine the coordination ability of the ligand, a single crystal of a copper(II) complex of the composition [CuLCl2] (IV) was obtained and studied by X-ray technique. Compounds I–III were studied using methods of X-ray phase analysis, electron (diffuse reflection spectra), infrared and Mössbauer spectroscopy, static magnetic susceptibility. The study of the µeff(T) dependence showed that the 1A1 ↔ 5T2 spin crossover manifests itself in the compounds. The spin crossover is accompanied by thermochromism: there is a distinct color change orange ↔ red-violet.
Databáze: OpenAIRE
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