Influence of Defects-Induced Stresses on Birefringence in SrTiO3 Single Crystals

Autor: Roleder, Iwona Lazar, Krzysztof Szot, Krystian
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Crystals; Volume 13; Issue 7; Pages: 985
ISSN: 2073-4352
DOI: 10.3390/cryst13070985
Popis: Significant applications of SrTiO3 single crystals in electronics require knowledge about the influence of structural imperfections on their optical properties. Birefringence temperature changes were investigated in a few SrTiO3 single crystals in a broad temperature range, from 85 K to 250 K. The birefringence was found to be a non-linear function below the transition Ts at 105 K, and non-linear changes in the optical indicatrix orientation accompanied it. A weak residual birefringence was permanently present a dozen degrees above the phase transition temperature Ts. This is mainly connected with dislocations, which induce local stresses and shift transition points even up to about 200 K. The essential role of imperfections on optical properties was studied in a SrTiO3 24° bi-crystal reduced at 1000 K and under low oxygen pressure. In such an intentionally defected crystal, an increase of non-linearities in Δn(T) dependence was observed below and above the transition point Ts.
Databáze: OpenAIRE