| Autor: |
Shibuya, Kengo, Koizumi, Masanori, Nishikido, Fumihiko, Saitou, Haruo, Kishimoto, Shunji |
| Jazyk: |
angličtina |
| Rok vydání: |
2009 |
| Zdroj: |
Acta Crystallographica. Section E, Structure Reports Online (Online Only URL:http://www.blackwell-synergy.com/loi/aye). 65(11):m1323-m1324 |
| ISSN: |
1600-5368 |
| Popis: |
Crystals of the title compound, {(C(6)H(5)C(2)H(4)NH(3))(2)[PbBr(4)]}(n), were grown at room temperature from a solution in N,N-dimethyl-formamide (DMF) using nitro-methane as the poor solvent. This perovskite-type organic-inorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr(6) octa-hedra separated by bilayers of phenethyl-ammonium cations. The octa-hedra are rotated and tilted due to N-H⋯Br hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetra-chloridoplumbate (C(6)H(5)C(2)H(4)NH(3))(2)[PbCl(4)]. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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