| Autor: |
Yano, Ryota, Yoshida, Masaki, Tsunenari, Takahiro, Sato-Tomita, Ayana, Nozawa, Shunsuke, Iida, Youhei, Matsunaga, Noriaki, Kobayashi, Atsushi, Kato, Masako |
| Jazyk: |
angličtina |
| Rok vydání: |
2021 |
| Zdroj: |
Dalton transactions. 50(25):8696-8703 |
| ISSN: |
1477-9226 |
| Popis: |
The nickel(ii)-chloranilato complex {Ni(ca)(VM)(2)}(n) (H(2)ca = chloranilic acid, VM = coordinated vapour molecules, such as water) shows reversible vapochromism upon exposure to various vapours and subsequent drying by heating. In contrast to the Ni(ii)-quinonoid complex, [Ni(HLMe)(2)] (H2LMe = 4-methylamino-6-methyliminio-3-oxocyclohexa-1,4-dien-1-olate), which was reported to exhibit vapochromic spin-state switching between high and low spin states, the chloranilato complex does not change its spin state even after the removal of coordinated vapour molecules. X-ray absorption fine structure (XAFS) analysis revealed that the six-coordinate geometry of {Ni(ca)(VM)(2)}(n) was maintained even after the removal of vapour molecules, in contrast to the [Ni(HLMe)(2)] complex. The unique vapochromism that follows the dimensional change between 1D and higher is influenced by the relatively weaker ligand field of the chloranilate ligand. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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