Host-guest chemistry between cyclodextrin and a hydrogen evolution catalyst cobaloxime

Autor: Kato, Masaru, Kon, Keita, Hirayama, Jun, Yagi, Ichizo
Jazyk: angličtina
Rok vydání: 2019
Zdroj: New journal of chemistry. 43(25):10087-10092
ISSN: 1144-0546
Popis: We report the host-guest chemistry between cyclodextrin and a bisdimethylglyoximato cobalt complex, cobaloxime. Cobaloxime forms a 1 : 1 host-guest assembly with beta- or gamma-cyclodextrin but not with alpha-cyclodextrin. The assembly of cobaloxime with gamma-cyclodextrin enhances the photocatalytic hydrogen evolution activity of a homogeneous system that contains an organic dye eosin Y in a neutral aqueous solution under visible-light irradiation.
Databáze: OpenAIRE