Light-melt adhesive based on dynamic carbon frameworks in a columnar liquid crystal phase

Autor: Saito, Shohei, Nobusue, Shunpei, Tsuzaka, Eri, Yuan, Chunxue, Mori, Chigusa, Hara, Mitsuo, Seki, Takahiro, Camacho, Cristopher, Irle, Stephan, Yamaguchi, Shigehiro
Jazyk: angličtina
Rok vydání: 2016
Zdroj: Nature Communications. 7
ISSN: 2041-1723
Popis: Liquid crystal (LC) provides a suitable platform to exploit structural motions of molecules in a condensed phase. Amplification of the structural changes enables a variety of technologies not only in LC displays but also in other applications. Until very recently, however, a practical use of LCs for removable adhesives has not been explored, although a spontaneous disorganization of LC materials can be easily triggered by light-induced isomerization of photoactive components. The difficulty of such application derives from the requirements for simultaneous implementation of sufficient bonding strength and its rapid disappearance by photoirradiation. Here we report a dynamic molecular LC material that meets these requirements. Columnar-stacked V-shaped carbon frameworks display sufficient bonding strength even during heating conditions, while its bonding ability is immediately lost by a light-induced self-melting function. The light-melt adhesive is reusable and its fluorescence colour reversibly changes during the cycle, visualizing the bonding/nonbonding phases of the adhesive.
Databáze: OpenAIRE