Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments
| Autor: | Nilesh C. Mehendale, Daniel E. Morse, William C. Kaska, Cornelis A. van Walree, Patrick O'Leary, Robertus J. M. Klein Gebbink, Gerard van Koten, Jan L. Sumerel |
|---|---|
| Rok vydání: | 2009 |
| Předmět: |
chemistry.chemical_classification
biology Chemistry Condensation biology.organism_classification Silicon Dioxide Cathepsins Catalysis Pincer movement Porifera Inorganic Chemistry Metal Demosponge Enzyme visual_art visual_art.visual_art_medium Organometallic Compounds Organic chemistry Animals Palladium Platinum |
| Zdroj: | Dalton transactions (Cambridge, England : 2003). (22) |
| ISSN: | 1477-9226 |
| Popis: | Silicatein protein filaments isolated from marine demosponges have been used to influence the condensation of siloxanes bearing organometallic pincer complexes. The siliceous material is formed under remarkably mild conditions and the organometallic pincer becomes an intrinsic part of the silica. The immobilisation of a metal pincer, which acts as a sensor and initial results on the immobilisation of a pre-catalytic pincer species are reported. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|