Syntheses and characterization of one-dimensional alkali metal antimony(III) thiostannates(IV), A2Sb2Sn3S10 (A=K, Rb, Cs)
| Autor: | Kanamaluru Vidyasagar, Jinu P. Yohannan |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Materials science
X ray diffraction chemistry.chemical_element Cesium Crystal structure Inorganic Chemistry Mossbauer symbols.namesake Antimony Mössbauer spectroscopy Materials Chemistry Physical and Theoretical Chemistry Isostructural Raman Cadmium compounds Coordination environment Thiostannate Condensed Matter Physics Alkali metal Oxidation state Electronic Optical and Magnetic Materials Energy gap Wide-band-gap semiconductor Crystallography Octahedron chemistry Tin Synthesis (chemical) X-ray crystallography Ceramics and Composites symbols Cadmium and leads Raman spectroscopy Spectroscopic measurements |
| Zdroj: | IndraStra Global. |
| ISSN: | 2381-3652 |
| DOI: | 10.1016/j.jssc.2014.10.022 |
| Popis: | Three new isostructural quaternary antimony(III) thiostannates(IV), A{sub 2}Sb{sub 2}Sn{sub 3}S{sub 10} (A=K, Rb, Cs) have been synthesized by using alkali metal thiosulfate flux and structurally characterized by X-ray diffraction. Their structures contain A{sup +} ions around the [Sb{sub 2}Sn{sub 3}S{sub 10}]{sup 2−} chains, which are built from SbS{sub 3} pyramids, SnS{sub 6} octahedra and SnS{sub 4} tetrahedra. Raman and Mossbauer spectroscopic measurements corroborate the oxidation states and coordination environments of Sb(III) and Sn(IV). All three compounds are wide band gap semiconductors. Potassium compound undergoes partial exchange with strontium, cadmium and lead ions. - Graphical abstract: Syntheses, crystal structure, spectroscopic and partial ion-exchange studies of new one-dimensional alkali metal antimony(III) thiostannates(IV), A{sub 2}Sb{sub 2}Sn{sub 3}S{sub 10} (A=K, Rb, Cs) are described. - Highlights: • Syntheses of new alkali metal antimony(III) thiostannates(IV), A{sub 2}Sb{sub 2}Sn{sub 3}S{sub 10} (A=K, Rb, Cs). • Wide band gap semiconductors with one-dimensional structure. • Topotactic partial exchange of K{sup +} ions of K{sub 2}Sb{sub 2}Sn{sub 3}S{sub 10} with Sr{sup 2+}, Cd{sup 2+} and Pb{sup 2+} ions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|