Assembly of the active center of organophosphorus hydrolase in metal-organic frameworks via rational combination of functional ligands
| Autor: | Quan-Guo Zhai, Caixia Zhuo, Yaodong Zhang, Mengfan Xia, Xuejuan Ma, Xiaohong Zhang, Hua-Ming Sun |
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| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Coordination sphere Base (chemistry) 010405 organic chemistry Chemistry Stereochemistry Metals and Alloys Rational design General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Active center chemistry.chemical_compound Hydrolase Materials Chemistry Ceramics and Composites Hydroxide Metal-organic framework Bimetallic strip |
| Zdroj: | Chemical communications (Cambridge, England). 53(82) |
| ISSN: | 1364-548X |
| Popis: | Different from popular mimics of bimetallic nuclear centers bridged by a hydroxide, a total coordination sphere of the active center of organophosphorus hydrolase was assembled in metal–organic frameworks by rational design and combination of ligands, which resulted in efficient destruction of nerve agent stimulants without a base as a co-catalyst. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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