Surfactant-templated silica doped with 1-phenyl-3-methyl-4-stearoylpyrazol-5-one (HPMSP) as a new sorbent
| Autor: | Maurice Leroy, Anne Boos, Jean-Pierre Brunette, Amarawan Intasiri |
|---|---|
| Přispěvatelé: | Institut Pluridisciplinaire Hubert Curien (IPHC), Université de Strasbourg (UNISTRA)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2002 |
| Předmět: |
Sorbent
Chemistry Inorganic chemistry Pyrazolone Cationic polymerization chemistry.chemical_element Sorption 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Copper 0104 chemical sciences Physisorption Pulmonary surfactant Materials Chemistry medicine [CHIM]Chemical Sciences Lamellar structure 0210 nano-technology ComputingMilieux_MISCELLANEOUS medicine.drug |
| Zdroj: | Journal of Materials Chemistry Journal of Materials Chemistry, Royal Society of Chemistry, 2002, 12 (4), pp.886-889. ⟨10.1039/B110659G⟩ |
| ISSN: | 1364-5501 0959-9428 |
| Popis: | A new sorbent for transition elements was prepared in a one-step synthesis by encapsulation of a pyrazolone ligand in a surfactant-templated silica. This new material was characterized by X-ray diffraction (XRD), nitrogen physisorption and transmission electron microscopy (TEM). The material presents a lamellar symmetry with a pore diameter of 39 A. The use of a cationic surfactant allows a high loading of ligand (0.43 mol kg−1), associated with complete accessibility of the ligand to the aqueous phase. A sorption capacity of 0.2 mol kg−1 was observed for copper ions in a NaNO3 0.01 M medium. Complete elution of copper species is possible with HNO3 1 M. |
| Databáze: | OpenAIRE |
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