Isolation and Characterization of a Carbene Derivative of La@C82

Autor:	Midori O. Ishitsuka, Satomi Takahashi, Takatsugu Wakahara, Yutaka Maeda, Kaoru Kobayashi, Takeshi Akasaka, Tadashi Hasegawa, Tatsuhisa Kato, Yoichiro Matsunaga, Michael T. H. Liu, Kazunori Yamamoto, Takahiro Tsuchiya, Kenji Yoza, Ernst Horn, Kisato Kokura, Shigeru Nagase, Shingo Okubo
Rok vydání:	2004
Předmět:	chemistry.chemical_compound Colloid and Surface Chemistry Chemistry Stereochemistry Metallofullerene General Chemistry Highly selective Biochemistry Carbene Catalysis Adduct
Zdroj:	Journal of the American Chemical Society. 126:6858-6859
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja0316115
Popis:	The photochemical reaction of La@C82 with 2-adamantane-2,3-[3H]-diazirine affords adduct 2, La@C82(Ad), in a quantitative and highly selective manner. The structure of compound 2 is confirmed by ESR, MS, and UV-vis-NIR spectroscopies, and the first X-ray crystallographic characterization of an endohedral monometallofullerene derivative is reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ff0e71aa3876e3b038dcb1496b534f15 https://doi.org/10.1021/ja0316115 Zobrazit plný text záznamu